劉彥祥 學術特聘教授 |
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通訊處 |
辦公室電話︰(02)2905-3570 實驗室電話:(02)2905-2482 |
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E-mail |
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學經歷 |
東吳大學化學系學士(1987) 美國Louisiana State University, Baton Rouge博士(1997) 田其芳股份有限公司光阻事業部總經理特助 中央研究院化學所博士後研究員 東吳大學化學系兼任助理教授 淡江大學化學系兼任助理教授 輔仁大學化學系助理教授 輔仁大學化學系副教授 輔仁大學化學系教授 輔仁大學化學系系主任(2018.8~2020.7) |
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獲獎紀錄 |
97學年度 理工學院教師及研究人員研究成果獎勵 98學年度 理工學院教師及研究人員研究成果獎勵 99學年度 理工學院教師及研究人員研究成果獎勵 100學年度 國家科學委員會特殊優秀人才獎勵 101學年度 國家科學委員會特殊優秀人才獎勵 102學年度 國家科學委員會特殊優秀人才獎勵 102學年度 國家科學委員會特殊優秀人才獎勵 103學年度 國家科學委員會特殊優秀人才獎勵 104學年度 國家科學委員會特殊優秀人才獎勵 105學年度 國家科學委員會特殊優秀人才獎勵 106學年度 國家科學委員會特殊優秀人才獎勵 |
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學術專長 |
無機化學 |
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研究領域 |
研究領域 本實驗室主要研究領域包含無機配位化學、固態化學以及超分子化學。研究範圍包含以下主題: 1, 單晶X-ray繞射結構解析 2. 晶體工程 3. 有機–無機混成多孔性吸附材料 4, 功能性固態光、電、磁自組裝配位聚合物 有機–無機混成配位聚合物之設計與合成: 設計與合成具有特殊幾何形狀與配位基之有機配子,與過渡金屬或鑭系金屬鹽類離子在受控制的水熱條件或室溫中進行超分子自組裝反應。藉有機配子的幾何形狀及金屬簇配位幾何結合,形成具特殊架構之固態結晶性配位聚合物(Scheme 1)。以單晶X-光繞射法進行晶體結構分析。並進而研究其因結構之多維架構特質導引之物理及化學性質。例如多孔性吸附、特殊之放光、離子導電、或磁性等性質的研究。 Scheme 1. 超分子自組裝配位聚合物之設計概念. Metal-Ligand Coordination: 研究室成果: |
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代表著作 |
1. Thanasekaran,
P.; Su, C. H.; Liu, Y. H.; Lu, K. L., Hydrophobic
Metal–Organic Frameworks and Derived Composites for Microelectronics
Applications. Chemistry – A European
Journal 2021, 27, 16543–16563. 2. Thanasekaran,
P.; Su, C. H.; Liu, Y. H.; Lu, K. L., Weak Interactions
in Conducting Metal–Organic Frameworks. Coordination
Chemistry Reviews 2021, 442, 213987. 3. Ngue, C. M.; Liu, Y. H.; Leung, M.; Lu, K. L., Reversible
Electroactive Behavior in a Zn-Based Metal–Organic Framework via Mild
Oxidation Potential. Inorganic
Chemistry 2021, 60, 11458–11465. 4. Hsu, K. T.; Thanasekaran, P.; Hsu, T. W.; Su, C. H.; Chang, B. C.; Liu, Y. H.; Hung, C. H.; Lu, K. L., A Nonlinear
Optical Cadmium(II)-Based Metal–Organic Framework with Chiral Helical Chains
Derived from an Achiral Bent Dicarboxylate Ligand. CrystEngComm 2021, 23, 824–830. 5. Wu, H. W.; Lee, L. W.; Thanasekaran, P.; Su, C. H.; Liu, Y. H.; Chin, T. M.; Lu, K. L., Weak
Interactions in Imidazole-Containing Zinc(II)-Based Metal–Organic Frameworks.
Journal of the Chinese Chemical Society
2020, 67, 2182–2188. 6. Inamdar, A. I.; Pathak, A.; Usman, M.; Chiou, K. R.; Tsai, P. H.; Mendiratta, S.; Kamal, S.; Liu, Y. H.; Chen, J. W.; Chiang, M. H.; Lu, K. L., Highly
Hydrophobic Metal–Organic Framework for Self-Protecting Gate Dielectrics. Journal of Materials Chemistry A 2020, 8, 11958–11965. 7. Usman, M.; Feng, P. H.; Chiou, K. R.; Chen, J. W.; Lee, L. W.; Liu, Y. H.; Lu, K. L., Polar Molecule
Confinement Effects on Dielectric Modulations of Sr-Based Metal–Organic
Frameworks. ACS Applied Electronic
Materials 2019, 1, 836–844. 8. Ngue, C. M.; Liu, Y. H.; Wen, Y. S.; Leung, M. K.; Chiu, C. W.; Lu, K. L., Spectroelectrochemical
Studies of the Redox Active Tris[4-(triazol-1-yl)phenyl]amine Linker and
Redox State Manipulation of Mn(II)/Cu(II) Coordination Frameworks. Dalton Transactions 2019, 48, 10122–10128. 9. Lee, L. W.; Kao, Y. C.; Chung, M. Y.; Chang, B. C.; Lee, G. H.; Peng, S. M.; Wang, C. M.; Liu, Y. H.; Lee, S. L.; Lu, K. L., Rare Metal-ion
Metathesis of a Tetrahedral Zn(II) Core of a Noncentrosymmetric
(3,4)-Connected 3D MOF. Dalton
Transactions 2019, 48, 1950–1954. 10. Ngue, C. M.; Chiu, C. W.; Lee, G. H.; Peng, S. M.; Leung, M. K.; Yang, C. I.; Liu, Y. H.; Lu, K. L., A Co(II) Framework
Derived from a Tris(4-(triazol-1-yl) phenyl) Amine Redox-Active Linker: An
Electrochemical and Magnetic Study. Dalton
Transactions 2018, 47, 9341–9346. 11. Lee, L. W.; Luo, T. T.; Lo, S. H.; Lee, G. H.; Peng, S. M.; Liu, Y. H.; Lee, S. L.; Lu, K. L.,
Pillared-Bilayer Zinc(II)–Organic Laminae: Pore Modification and Selective
Gas Adsorption. CrystEngComm 2015, 17, 6320–6327. 12. Peng, Y. R.; Chien, P. H.; Chung, H. T.; Pan, P. Y.; Liu, Y. H.; Yang, E. C., Studies of
the Structural and Magnetic Properties of an Unsymmetrical Ligand
1,2,4-Benzenetricarboxylic acid Based Chiral 3-D Trinickel Coordination
Polymer as an Alkali Base-Influenced Hydrothermal Reaction Product. Journal of Solid State Chemistry 2014, 212, 159–164. 13. Liu, Y. H.; Chien, P. H., A
Series of Lanthanide–Organic Frameworks Possessing Arrays of 2D Intersecting
Channels within a 3D Pillar-Supported Packed Double-Decker Network and Co2+-Induced
Luminescence Modulation. CrystEngComm 2014, 16, 8852–8862. 14. Liu, Y. H.; Peng, C. C.; Lee, S. H.; Chien, P. H.; Wu, P. C., In situ
Resolved Ligand Chirality in Preparing a Chiral 3D
Zinc-Cyclopentane-Tetracarboxylate Based Coordination Polymer. CrystEngComm 2013, 15, 10333–10339. 15. Liu, Y. H.; Lee, S. H.; Chiang, J. C.; Chen, P. C.; Chien, P. H.; Yang, C. I., Dehydration
Induced 2D-to-3D Crystal-to-Crystal Network Re-assembly and Ferromagnetism
Tuning within Two Chiral Copper(II)-Tartrate Coordination Polymers. Dalton Transactions 2013, 42, 16857–16867. 16. Lee, C. H.; Huang, H. Y.; Liu, Y. H.; Luo, T. T.; Lee, G. H.; Peng, S. M.; Jiang, J. C.; Chao, I.; Lu, K. L., Cooperative
Effect of Unsheltered Amide Groups on CO2 Adsorption Inside
Open-Ended Channels of a Zinc(II)–Organic Framework. Inorganic Chemistry 2013,
52, 3962–3968. 17. Chung, H. T.; Yang, C. I.; Yang, E. C.; Peng, C. C.; Tsai, H. L.; Liu, Y. H., Metamagnetic
Behavior and Moisture-Absorption Induced Reversible Network Assembly of a
Cobalt-1,2,4-Benzenetricarboxylate Supramolecular Network. CrystEngComm 2012, 14, 1317–1323. 18. Chang, C. C.; Huang, Y. C.; Huang, S. M.; Wu, J. Y.; Liu, Y. H.; Lu, K. L., Presynthesized
and In-Situ Generated Tetrazolate Ligand in the Design of Chiral Cadmium
Coordination Polymer. Crystal Growth
& Design 2012, 12, 3825–3828. 19. Yang, C. I.; Song, Y. T.; Yeh, Y. J.; Liu, Y. H.; Tseng, T. W.; Lu, K. L., A Flexible
Tris-Phosphonate for the Design of Copper and Cobalt Coordination Polymers:
Unusual Cage Array Topology and Magnetic Properties. CrystEngComm 2011, 13, 2678–2686. 20. Liu, Y. H.; Fang, H. P.; Jhang, P. C.; Peng, C. C.; Chien, P. H.; Yang, H. C.; Huang, Y. C.; Lo, Y. L., A New
Cd-4-2,4-Pyridinedicarboxylate Layered Coordination Polymer Consisting of
Intralayer Cavities and Reversible Network Self-Adaptation upon
Dehydration/Moisture-Absorption. CrystEngComm
2010, 12, 1779–1783. 21. Wu, J. Y.; Ding, M. T.; Wen, Y. S.; Liu, Y. H.; Lu, K. L., Alkali Metal
Cation (K+, Cs+) Induced Dissolution/Reorganization of
Porous Metal Carboxylate Coordination Networks in Water. Chemistry – A European Journal 2009, 15, 3604–3614. 22. Lin, Y. C.; Chen, W. T.; Tai, J.; Su, D.; Huang, S. Y.; Lin, I.; Lin, J. L.; Lee, M. M.; Chiou, M. F.; Liu, Y. H.; Kwan, K. S.; Chen, Y. J.; Chen, H. Y., Tuning
Through-Bond Fe(III)/Fe(II) Coupling by Solvent Manipulation of a Central
Ruthenium Redox Couple. Inorganic
Chemistry 2009, 48, 1857–1870. 23. Ding, M. T.; Wu, J. Y.; Liu, Y. H.; Lu, K. L.,
Dissolution/Reorganization toward the Destruction/Construction of Porous
Cobalt(II)- and Nickel(II)-Carboxylate Coordination Polymers. Inorganic Chemistry 2009, 48, 7457–7465. 24. Chung, H. T.; Tsai, H. L.; Yang, E. C.; Chien, P. H.; Peng, C. C.; Huang, Y. C.; Liu, Y. H., A New
Manganese Coordination Polymer Containing 1,2,4-Benzenetricarboxylic Acid. Chemistry – A European Journal 2009, 3661–3666. 25. Wu, J. Y.; Yang, S. L.; Luo, T. T.; Liu, Y. H.; Cheng, Y. W.; Chen, Y. F.; Wen, Y. S.; Lin, L. G.; Lu, K. L., Time-Evolving
Self-Organization and Autonomous Structural Adaptation of Cobalt(II)-Organic
Framework Materials with scu and pts Nets. Chemistry – A European Journal 2008, 14, 7136–7139. 26. Tsai, C. J.; Liu, Y. H.,
Poly[diaquabis(2,2 '-bipyridine)tris(mu(4-)2,2 '-bipyridine-4,4
'-dicarboxylato)-dineodymium(III)]. Acta
Crystallographica Section E-Crystallographic Communications 2008, 64, M260-U2441. 27. Luo, T. T.; Liu, Y. H.; Chan, C. C.; Huang, S. M.; Chang, B. C.; Lu, Y. L.; Lee, G. H.; Peng, S. M.; Wang, J. C.; Lu, K. L., Toward Quartz
and Cristobalite: Spontaneous Resolution, Structures, and Characterization of
Chiral Silica-Mimetic Silver(I)–Organic Materials. Inorganic Chemistry 2007,
46, 10044–10046. 28. Liu, Y. H.; Jhang, P. C.,
Catena-Poly[[[diaquanickel(II)]-mu-pyridine-2,4-dicarboxylato-[tetraaquanickel(II)]-mu-pyridine-2,4-dicarboxylato]
dihydrate]. Acta Crystallographica
Section E-Crystallographic Communications 2007, 63, M1682-U961. 29. Liu, Y. H.; Ding, M. T.,
Poly[[tetraaqua(mu(6)-benzene-1,2,4,5-tetracarboxylato)dicobalt(II)]
dihydrate]. Acta Crystallographica
Section E-Crystallographic Communications 2007, 63, M1828-U554. |